熊耳山地区上道回钼矿地质特征及成矿流体演化
发布时间:2018-01-19 19:26
本文关键词: 上道回钼矿 钾长石—石英脉型 地质特征 成矿流体 熊耳山 出处:《中国地质大学(北京)》2016年硕士论文 论文类型:学位论文
【摘要】:河南嵩县上道回钼矿位于豫西熊耳山—外方山地区,控矿断层为马超营断裂次级断裂,产出地层为熊耳群中酸性—中基性火山岩,矿体沿垂向上多层脉状体产出。矿石金属矿物以辉钼矿、黄铁矿为主,少量闪锌矿、方铅矿、黄铜矿等,围岩蚀变以硅化、钾长石化为主,晚阶段可见少量碳酸盐化。上道回钼矿床从早阶段到晚晚阶段分为三个阶段:石英-黄铁矿阶段,石英-辉钼矿-多金属硫化物阶段,石英-方解石阶段。流体包裹体类型为C型(CO_2型)、W型(NaCl-H_2O型)、S型(含子晶型)。早、中阶段发育NaCl-H_2O型、CO_2型和少量含子晶型包裹体,晚阶段发育NaCl-H_2O型。流体包裹体均一温度从早到晚为210—390℃、180—300℃、120—220℃,盐度由早阶段1.0%—13.4%和27.2%—33.2%,经中阶段0.3%—14.1%和27.3%—28.5%,到晚阶段0.1%—14.2%。成矿流体由富CO_2向贫CO_2演化,流体沸腾作用使二氧化碳等挥发分逃逸,造成成矿流体pH值升高、还原性增强,导致成矿物质的沉淀。成矿早阶段及成矿中阶段CO_2型流体包裹体的捕获压力为148—371 MPa、108—383 MPa,相对应的成矿深度为5.5—13.8 km和4.0—14.2 km,表明成矿深度为5—14 km。氢-氧同位素投图中,石英中的δ~(18)O值变化范围9.7‰—14.1‰,计算得到δ~(18)OH_2O的变化范围为0.38‰—5.14‰;流体的dD值变化范围为-83‰—-73‰。流体的H-O同位素组成呈现出由变质水/岩浆水—雨水线的演化。C-O同位素显示,δ13CPDB值介于-6.3‰—-11.8‰,平均值为-8.2‰,且均为负值。C-O同位素投点图显示出由花岗岩向海相碳酸盐岩递进的趋势,表明C-O同位素的来源可能来自于岩浆热液或者区内官道口群、栾川群等碳酸盐地层。黄铁矿的δ34S测试结果集中在-8‰—-6‰,只有一个数据为-14.7‰,且δ34S均为负值,这与熊耳山地区太华群、熊耳群地层中δ34S呈双峰(1‰—3‰,4‰—6‰)不同,地层中黄铁矿的δ34S均为正值,表明上道回钼矿的硫不应该只是上述地层中的硫。通过对比发现,矿床的形成时代应属于中生代,属典型的造山成矿时代背景,形成于中生代秦岭造山带由碰撞挤压向伸展的转变期。通过流体包裹体及C、H、O、S等稳定同位素的研究,结合区域地质背景,认为上道回钼矿应属于陆陆碰撞体制的断控造山型钼矿,其矿床形成机制可用CMF模式来解释。
[Abstract]:Henan Songxian on the road to molybdenum deposit is located in XIONGERSHAN Waifangshan region in the west of Henan Province, ore controlling fault is camp Ma Chao fracture and secondary fracture, formation for the Xiong'er Group in acid - base volcano rock, ore body to the multilayer vein along the vertical output. The metal minerals in molybdenite, pyrite, sphalerite, galena, little. Chalcopyrite, wall rock alteration, silicification, potash feldspathization, late stage a small amount of carbonation. On the road back to the molybdenum deposit from early stage to late stage is divided into three stages: Quartz pyrite stage, quartz molybdenite polymetallic sulfide stage, quartz calcite. Fluid inclusions type C type (CO_2 type), W type (NaCl-H_2O type), S type (including sub crystal). In the early stage of development, NaCl-H_2O type, CO_2 type and a small amount of sub crystal inclusions, the late developmental stage of NaCl-H_2O. The homogenization temperature of fluid inclusions is 210 - 390 degrees from 18. 0鈥,
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