主链或侧链含二茂铁的聚合物的合成和应用

发布时间：2018-01-11 22:35

本文关键词：主链或侧链含二茂铁的聚合物的合成和应用　出处：《化学进展》2016年01期 　论文类型：期刊论文

【摘要】：由于二茂铁基聚合物独特的结构和性能,其在电化学、生物医学及光学等领域具有广阔应用前景。开发新型二茂铁基聚合物并探索其应用已经成为科研工作者的研究热点。本文主要综述主链或侧链含二茂铁的聚合物的合成及应用。其中合成主链含二茂铁的聚合物的方法主要有缩聚法和开环聚合法等。合成侧链含二茂铁的聚合物的方法主要有自由基聚合法、原子转移自由基聚合法和可逆加成断裂链转移聚合法等。最后,对二茂铁基聚合物的应用前景进行了展望。
[Abstract]:Because the two ferrocenyl polymer structure and unique properties, it has a broad application prospect in electrochemistry, biomedicine and optics. The development of new two ferrocene based polymers and explore its application has become the research focus. The synthesis and application of ferrocene containing two this paper focuses on the main chain or side chain polymers. The synthesis method the main chain containing two ferrocene polymers include condensation polymerization and ring opening polymerization method. Methods two containing ferrocene synthesis of side chain polymers include free radical polymerization, atom transfer radical polymerization and reversible addition fragmentation chain transfer polymerization. Finally, application prospect of two ferrocene based polymers are discussed.

【作者单位】：浙江大学化学工程与生物工程学院化学工程联合国家重点实验室;
【分类号】：O634
【正文快照】： *Corresponding author e-mail:opl_wl@dial.zju.edu.cn;wdzhou1229@163.comContents1 Introduction2 Synthesis of main-chain ferrocene-based polymers2.1 Polycondensation reaction2.2 Ring-opening polymerization3 Synthesis of side-chain ferrocene-based polymers3.

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