UiO系列金属-有机骨架的合成方法与应用

发布时间：2018-04-11 02:31

  本文选题：金属-有机骨架 + UiO系列　； 参考：《无机化学学报》2017年05期

【摘要】：本文综述了包括UiO-66、UiO-67和UiO-68在内的UiO系列金属-有机骨架(MOFs)材料的合成方法、结构特点及各类应用。系统介绍了利用包括扩散法、溶剂热法、微波辅助法、机械研磨法、持续流合成法及电化学合成法等方法合成UiO系列MOFs材料的反应条件、产物特征及优缺点。UiO系列MOFs因稳定的Zr-O键及超高的配位数而具有超高热稳定性和化学稳定性等,其在化学催化、光催化、气体吸附、气体分离、液相吸附有机污染物、荧光、传感、医学和电容器等方面均具有十分广泛的应用。同时,本文还根据UiO系列MOFs材料的研究现状对其未来发展趋势进行了展望。
[Abstract]:In this paper, the synthetic methods, structural characteristics and various applications of UiO series of metal-organic framework MOFs, including UiO-66, UiO-67 and UiO-68, are reviewed.The reaction conditions for the synthesis of UiO series MOFs materials by means of diffusion method, solvothermal method, microwave assisted method, mechanical grinding method, continuous flow synthesis method and electrochemical synthesis method are introduced systematically.Product characteristics and advantages and disadvantages. UiO series MOFs has high thermal stability and chemical stability due to its stable Zr-O bond and high coordination number. It is widely used in chemical catalysis, photocatalysis, gas adsorption, gas separation, liquid phase adsorption of organic pollutants, fluorescence, etc.Sensing, medicine and capacitors are widely used.At the same time, according to the research status of UiO series MOFs materials, the future development trend is prospected.
【作者单位】： 北京建筑大学建筑结构与环境修复功能材料北京市重点实验室;北京建筑大学城市雨水系统与水环境教育部重点实验室;
【基金】：国家自然科学基金(No.51578034) 北京自然科学基金重点项目B类(No.KZ201410016018) 北京百千万人才工程培养经费(No.2016023)资助项目
【分类号】：O641.4;TB383
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本文编号：1734057