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“碳龙同花顺”的重要一环:金属桥位三并五元环的构筑

发布时间:2018-09-11 12:35
【摘要】:正Angew.Chem.Int.Ed.2017,56,9067~9071金属杂芳香化学是金属有机化学和芳香化学的纽带.2013年,厦门大学化学化工学院夏海平、朱军等首次报道了一类全新的平面型M?bius芳香体系——金属杂戊搭炔I(Nat.Chem.2013,5,698).在此基础上,一系列金属桥位多环分子骨架被报道,逐步建立了厦门大学独特的"碳龙化学".包括金属杂戊搭烯I、金属杂戊搭烯并三元环II、
[Abstract]:In 2013, Xia Haiping and Zhu Jun, School of Chemical Technology, Xiamen University, reported for the first time a new kind of planar M?bius aromatic system-Metallic pentylene-I (Nat.Chem.2013,5698). On this basis, a series of metal bridging polycyclic molecular skeletons were reported, and the unique "Carbonion-Chemistry" of Xiamen University was gradually established. Including Metallic Heteropentene I, Metallic Heteropentene ternary II,
【分类号】:O627


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