可见光引发的无金属的惰性键选择性官能化研究
发布时间：2018-11-07 18:48
【摘要】：正Angew.Chem.,Int.Ed.2017,56,12619~12623烷氧自由基是化学与生物研究中重要的活性中间体,然而传统条件下产生烷氧自由基需要加热、强氧化剂、紫外光照射等剧烈反应条件.近年来烷氧自由基被发现可以在温和的可见光氧化还原条件下产生,然而目前仍需要使用重金属光催化剂,对于药物合成、材料科学、生命科学的应用带来了困难.中国科学院上海有机化学研究所生命
[Abstract]:Angew.Chem.,Int.Ed.2017,56,12619~12623 alkoxy radical is an important active intermediate in chemical and biological research. However, the production of alkoxy radical under traditional conditions needs heating, strong oxidant, ultraviolet irradiation and other severe reaction conditions. In recent years, alkoxy free radicals have been found to be produced under mild visible light redox conditions. However, heavy metal photocatalysts are still needed, which makes it difficult for the application of drug synthesis, material science and life science. Life of Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences
【分类号】：O621.25
本文编号：2317266
[Abstract]:Angew.Chem.,Int.Ed.2017,56,12619~12623 alkoxy radical is an important active intermediate in chemical and biological research. However, the production of alkoxy radical under traditional conditions needs heating, strong oxidant, ultraviolet irradiation and other severe reaction conditions. In recent years, alkoxy free radicals have been found to be produced under mild visible light redox conditions. However, heavy metal photocatalysts are still needed, which makes it difficult for the application of drug synthesis, material science and life science. Life of Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences
【分类号】：O621.25
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