2-乙酰吡嗪缩肼基甲酸甲酯的镍和镉配合物的晶体结构及荧光性质（英文）
发布时间：2019-01-09 15:12
【摘要】：合成并通过X射线单晶衍射、元素分析及红外光谱表征了配合物[Ni(L)_2](1)和[Cd(HL)(CH_3OH)(NO_3)_2](2)的结构(HL为2-乙酰吡嗪缩肼基甲酸甲酯)。单晶衍射结果表明,配合物1中,Ni(Ⅱ)离子与来自2个阴离子配体L-的N_2O电子供体配位,形成扭曲的八面体配位构型。在配合物2中,Cd(Ⅱ)离子拥有双帽三棱柱配位构型,与1个中性配体HL,2个双齿配位硝酸根和1分子甲醇配位。此外还研究了配合物1和2的荧光及热性质。
[Abstract]:Synthesis and diffraction of X-ray single crystals, The structures of the complexes [Ni (L) _ 2] (1) and [Cd (HL) (CH_3OH) (NO_3) _ 2] (2) were characterized by elemental analysis and IR spectra. The results of single crystal diffraction show that the, Ni (鈪，
本文编号：2405790
[Abstract]:Synthesis and diffraction of X-ray single crystals, The structures of the complexes [Ni (L) _ 2] (1) and [Cd (HL) (CH_3OH) (NO_3) _ 2] (2) were characterized by elemental analysis and IR spectra. The results of single crystal diffraction show that the, Ni (鈪，
本文编号：2405790
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