碳龙配合物的烯基化研究
发布时间：2019-03-31 07:50
【摘要】：碳龙配合物是一类崭新的金属杂芳香化合物,具有新颖的结构和独特的性能,有着很好的潜在应用前景.然而,已报道的碳龙配合物绝大部分不带有可进一步化学修饰的有机官能团.此状况阻碍了其进一步化学修饰和实现功能材料化的应用研究.烯烃基团是一类高活性有机官能团——可发生高转化率的聚合反应、点击反应等多种有机反应.为此,合成烯基化的碳龙配合物,可实现这类新颖分子的有机功能团化,对其后续实际应用有着重要的意义和价值.利用锇杂戊搭炔的反应性以及合成底物的修饰,设计合成了一系列烯基化的碳龙配合物,并对其进行了系统表征.
[Abstract]:Carbon dragon complex is a new class of metal hetero-aromatic compounds with novel structure and unique properties, and has a good potential application prospect. However, most of the reported carbon dragon complexes do not contain further chemically modified organic functional groups. This situation hinders the further chemical modification and the application of functional materials. Olefin group is a kind of highly active organic functional group-many kinds of organic reactions, such as high conversion polymerization, click reaction and so on. Therefore, the synthesis of alkylated carbon dragon complexes can realize the organic functional grouping of these novel molecules, which is of great significance and value for its subsequent practical application. A series of alkenated carbon dragon complexes were designed and synthesized by using the reactivity of osmium heteropentynes and modification of synthetic substrates, and their systematic characterization was carried out.
【作者单位】： 厦门大学化学化工学院;厦门大学材料学院;
【基金】：国家自然科学基金(Nos.21490573,21332002,21472156)资助项目~~
【分类号】：O641.4
，
本文编号：2450711
[Abstract]:Carbon dragon complex is a new class of metal hetero-aromatic compounds with novel structure and unique properties, and has a good potential application prospect. However, most of the reported carbon dragon complexes do not contain further chemically modified organic functional groups. This situation hinders the further chemical modification and the application of functional materials. Olefin group is a kind of highly active organic functional group-many kinds of organic reactions, such as high conversion polymerization, click reaction and so on. Therefore, the synthesis of alkylated carbon dragon complexes can realize the organic functional grouping of these novel molecules, which is of great significance and value for its subsequent practical application. A series of alkenated carbon dragon complexes were designed and synthesized by using the reactivity of osmium heteropentynes and modification of synthetic substrates, and their systematic characterization was carried out.
【作者单位】： 厦门大学化学化工学院;厦门大学材料学院;
【基金】：国家自然科学基金(Nos.21490573,21332002,21472156)资助项目~~
【分类号】：O641.4
，
本文编号：2450711
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