结晶性的多孔高分子-金属配合物的最新研究进展——合成、表征和性质（英文）
发布时间：2019-04-02 01:02
【摘要】：由于高分子具有尺寸长短不一、柔性等特点,很难通过普通方法合成具有结晶性和多孔性的高分子材料。而高分子金属配合物材料不仅继承了高分子材料的传统性质,同时也可以获得配合物的优点,比如高结晶性和多孔性。本文系统总结了合成结晶性的多孔高分子配合物材料的方法,包括光诱导聚合法、配位自主装法、分步合成法以及后修饰法。同时介绍了它们的表征方法以及潜在应用领域,并讨论了该领域研究中存在的各种机遇与挑战。
[Abstract]:It is difficult to synthesize crystalline and porous polymer materials by ordinary method because of their different size and flexibility. The polymer metal complex material not only inherits the traditional properties of the polymer material, but also can obtain the advantages of the complex, such as high crystallinity and porosity. In this paper, the synthesis methods of crystalline porous polymer complexes are summarized systematically, including photoinduced polymerization, coordination self-loading, step-by-step synthesis and post-modification. At the same time, their characterization methods and potential application fields are introduced, and the opportunities and challenges existing in this field are also discussed.
【作者单位】： 南开大学化学学院;药物化学生物学国家重点实验室南开大学;南开大学药学院;
【基金】：the China Young 1000 Talents program NSFC (Grant No.21601093)~~
【分类号】：O641.4
本文编号：2452077
[Abstract]:It is difficult to synthesize crystalline and porous polymer materials by ordinary method because of their different size and flexibility. The polymer metal complex material not only inherits the traditional properties of the polymer material, but also can obtain the advantages of the complex, such as high crystallinity and porosity. In this paper, the synthesis methods of crystalline porous polymer complexes are summarized systematically, including photoinduced polymerization, coordination self-loading, step-by-step synthesis and post-modification. At the same time, their characterization methods and potential application fields are introduced, and the opportunities and challenges existing in this field are also discussed.
【作者单位】： 南开大学化学学院;药物化学生物学国家重点实验室南开大学;南开大学药学院;
【基金】：the China Young 1000 Talents program NSFC (Grant No.21601093)~~
【分类号】：O641.4
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