基于修饰的β-环糊精的超分子体系研究及应用进展
发布时间：2019-04-24 09:31
【摘要】：β-环糊精是一类环状的、由7个D-吡喃葡萄糖单元通过α-1,4-糖苷键连接而成的低聚糖,具有"内疏水、外亲水"的刚性锥形空腔结构。近年来,基于β-环糊精的超分子体系的制备及应用取得前所未有的显著进展。本文主要综述了β-环糊精衍生物、低聚物以及多聚物在合成方面的新进展,介绍了基于β-环糊精的分子组装,以及以β-环糊精及其修饰物为超分子主体的超分子体系在药物运输、基因传递、催化反应、污染治理等方面的最新应用。目前,对β-环糊精基本性质及应用的研究已日趋成熟,但仍存在许多实际性的问题需要解决。随着研究的进一步深入,有望实现β-环糊精在各领域的大规模、深层次应用。
[Abstract]:尾-cyclodextrin (尾-cyclodextrin) is a kind of circular oligosaccharides composed of seven D-glucopyranose units linked by 伪-1, 4-glucoside bonds. It has a rigid conical cavity structure of "internal hydrophobic, external hydrophilic". In recent years, the preparation and application of supramolecular systems based on 尾-cyclodextrin have made unprecedented progress. In this paper, the recent progress in the synthesis of 尾-cyclodextrin derivatives, oligomers and polymers is reviewed, and the molecular assembly based on 尾-cyclodextrin is introduced. And the latest application of supramolecular system with 尾-cyclodextrin and its modifiers as supramolecular agents in drug transport, gene transfer, catalytic reaction, pollution control and so on. At present, the research on the basic properties and application of 尾-cyclodextrin has become more and more mature, but there are still many practical problems to be solved. With the further research, it is expected to realize the large-scale and deep-seated application of 尾-cyclodextrin in various fields.
【作者单位】： 中国石油大学(华东)重质油国家重点实验室;
【基金】：国家自然科学基金资助项目(21376265)~~
【分类号】：O641.3;O636.12
[Abstract]:尾-cyclodextrin (尾-cyclodextrin) is a kind of circular oligosaccharides composed of seven D-glucopyranose units linked by 伪-1, 4-glucoside bonds. It has a rigid conical cavity structure of "internal hydrophobic, external hydrophilic". In recent years, the preparation and application of supramolecular systems based on 尾-cyclodextrin have made unprecedented progress. In this paper, the recent progress in the synthesis of 尾-cyclodextrin derivatives, oligomers and polymers is reviewed, and the molecular assembly based on 尾-cyclodextrin is introduced. And the latest application of supramolecular system with 尾-cyclodextrin and its modifiers as supramolecular agents in drug transport, gene transfer, catalytic reaction, pollution control and so on. At present, the research on the basic properties and application of 尾-cyclodextrin has become more and more mature, but there are still many practical problems to be solved. With the further research, it is expected to realize the large-scale and deep-seated application of 尾-cyclodextrin in various fields.
【作者单位】： 中国石油大学(华东)重质油国家重点实验室;
【基金】：国家自然科学基金资助项目(21376265)~~
【分类号】：O641.3;O636.12
【参考文献】
相关期刊论文 前3条
1 李惠梅;王洁;倪云洲;周永丰;颜德岳;;“线性-超支化”超分子聚合物的制备及光响应性自组装行为研究[J];化学学报;2016年05期
2 ;Electrochemically sensitive supra-crosslink and its corresponding hydrogel[J];Science China(Chemistry);2012年05期
3 廖萍;何平;王玉;姜天s，
本文编号：2464338
本文链接：https://www.wllwen.com/kejilunwen/huaxue/2464338.html
教材专著
