自组装策略调控表面反应
发布时间：2019-05-19 10:20
【摘要】：正表面反应,即在固体表面发生的化学反应,一直是化学学科的研究焦点。近年来,人们借助扫描隧道显微镜(STM)等表面分析技术,在表面上成功实现大量的有机反应如Ullmann偶联~1、Glaser偶联~2和Bergman环化~3等。表面反应涉及到固体表面结构和反应分子本征性质,就像一个硬币的两个方面。固体表面具有催化活性的增原子、表面平台和台阶、表面限域和晶格诱导效应等~(4-7)均可对表面反应进行有效
[Abstract]:Positive surface reaction, that is, chemical reaction on solid surface, has always been the focus of chemistry. In recent years, with the help of scanning tunneling microscope (STM) and other surface analysis techniques, a large number of organic reactions such as Ullmann coupling ~ 1, Glaser coupling ~ 2 and Bergman cyclization ~ 3 have been successfully realized on the surface. Surface reaction involves solid surface structure and intrinsic properties of reaction molecules, just like two aspects of a coin. ~ (4 鈮，
本文编号：2480642
[Abstract]:Positive surface reaction, that is, chemical reaction on solid surface, has always been the focus of chemistry. In recent years, with the help of scanning tunneling microscope (STM) and other surface analysis techniques, a large number of organic reactions such as Ullmann coupling ~ 1, Glaser coupling ~ 2 and Bergman cyclization ~ 3 have been successfully realized on the surface. Surface reaction involves solid surface structure and intrinsic properties of reaction molecules, just like two aspects of a coin. ~ (4 鈮，
本文编号：2480642
本文链接：https://www.wllwen.com/kejilunwen/huaxue/2480642.html
教材专著
