Si对压力容器钢低温韧性的影响
发布时间:2018-04-08 15:59
本文选题:压力容器钢 切入点:Si 出处:《武汉科技大学》2013年硕士论文
【摘要】:研究了Si对Nb-Ti微合金化3.5Ni低温压力容器用钢和Cr-Mo合金化中温压力容器用钢低温韧性的影响。结果表明,降低Si含量提高了压力容器钢低温韧性,这主要因为低Si试样中析出的渗碳体细化了依附其析出的合金碳化物;细小弥散分布的回火碳化物改善了低温韧性。 对于830℃正火+630℃回火的Nb-Ti微合金钢,主要结果为:在830℃正火+630℃回火条件下,,0.05%和0.47%Si试样组织均为贝氏体和等轴铁素体。当Si含量从0.05%增至0.47%时,(Nb,Ti)C(小于10nm)比例从53.5%降至26.2%,(Nb,Ti)C(大于30nm)比例从13.0%增至54.1%,0.05%Si和0.47%Si试样平均尺寸分别为11.2nm和25.1nm。高分辨透射电镜观察发现,在0.05%Si试样中,(Nb,Ti)C在渗碳体上析出。在不同冲击温度(-90~-130℃)下,0.05%Si试样平均夏比冲击功均高于0.47%Si试样。扫描电镜观察-110℃时冲击断口发现,不同Si试样均为韧性断口,0.05%Si试样韧窝数量较多较细小。玻尔兹曼拟合函数表明,0.05%Si和0.47%Si试样韧脆转变温度分别为-105.1℃和-115.4℃,低Si韧脆转变温度更低。 对于1000℃正火+650℃回火的Cr-Mo合金化钢,主要结果为:0.54%Si和1.55%Si试样组织均为贝氏体+铁素体。透射电镜观察发现,0.54%Si试样析出物为M6C和M23C6,1.55%Si试样析出物为M7C3和M23C6。当Si含量从0.54%增至1.55%时,析出粒子平均尺寸从50nm增至200nm,平均夏比冲击功从158J降至83J。
[Abstract]:The effect of Si on the low temperature toughness of Nb-Ti microalloyed 3.5Ni low temperature pressure vessel steel and Cr-Mo alloyed medium temperature pressure vessel steel was studied.The results show that the low temperature toughness of pressure vessel steel is improved by decreasing Si content, which is mainly due to the addition of cemented carbides in low Si samples to the refinement of the alloy carbides which are dependent on them, and the low temperature toughness is improved by the fine dispersed tempered carbides.For Nb-Ti microalloyed steel tempered at 630 鈩
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