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低阶煤孔隙特征与解吸规律研究

发布时间:2017-01-02 15:07

  本文关键词:低阶煤孔隙特征与解吸规律研究,由笔耕文化传播整理发布。


西安科技大学

硕士学位论文

低阶煤孔隙特征与解吸规律研究

姓名:乔军伟

申请学位级别:硕士

专业:矿产普查与勘探

指导教师:马东民

20090513

论文题目:低阶煤孔隙特征与解吸规律研究

专业:矿产普查与勘探

硕士生:乔军伟

指导教师:马东民(签名)盎垦经(签名)坦型

摘要

目前我国煤层气勘探开发主要集中在中、高阶煤地区,低阶煤煤层气的勘探和开发技术及相应的研究十分薄弱。我国的低阶煤(RoS0.65%)分布十分广泛,以新疆、内蒙、陕西、青海、宁夏为主。由于低阶煤的孔隙结构与中、高阶煤有较大的差异,煤层气的吸附和解吸特性具有不同于中、高阶煤的特点,同时由于采煤活动频度增强,矿井瓦斯成为这些矿区最大的安全隐患,有必要对现阶段我国低阶煤煤层气开发区进行解吸特性的深入认识。

对低阶煤煤层气勘探开发区煤层气解吸特性的认识,要从煤层气储层的物性特征分析入手,进行工业分析、煤岩组分鉴定与煤岩类型划分、孔隙度测定、扫描电镜观察、孔隙分布与孔喉特征的压汞实验、比表面积测定与孔容测定的液氮吸附实验、等温吸附实验,在物理性质分析的基础上进行等温降压解吸实验与升温解吸实验,揭示煤层气解吸规律并归纳数学模型,为扩散、渗流的深入研究奠定基础。

通过系统的实验和分析总结,笔者认为:我国低阶煤的孔隙主要由大孔和中孔构成,总体上反映出半封闭孔隙和细瓶颈孔隙形态,部分反映出半封闭孔隙的特征,比表面积在5"--'6nm和50"--'60nm两处显著分布:低阶煤的吸附能力总体低于中、高阶煤,,褐煤的吸附能力低于长焰煤,Weibull函数对低阶煤吸附曲线的拟合度最高;低阶煤中甲烷的解吸率大多高于中、高阶煤,Weibull函数对低阶煤解吸曲线的拟合度最高。最后,分析和总结了低阶煤煤层气吸附/解吸的影响因素。

关键词:低阶煤:吸附;解吸;Weibull函数研究类型:理论研究

Subject:ResearchontheLowRankCoalofPoreCharacteristicsand

DesorptionLaws

Specialty:MineralSurvey

:QiaoJunweiandExplorationName(signature)Qi趾j丛△丝}

(signature)Instructor:MaDongrain

ABSTRACT

T11eexplorationandexploitationofcoal—bedmethane(CBM)mainlyconcentratedinmediumrankand11ighrankcoalareapresentlyinChina.It’SveryweaktheexplorationanddevelopmentoflowrankCBMandthecorrespondingresearchtechnique.Lowrankcoal(Ro<O.65%)isveryextensiveinchina,suchasxinjiang,InnerMongolia,shaanxi,ningxia,

differentofmiddleandhigh.ordercoal。The

coalbedqinghai.Theporeadsorptionandstructureoflowrankcoalisdesorption

tocharacteristicsofmethanealsohavedifferentcharacteristics.Due

hiddenminingactivitiesoffrequency,minegasbecamethebiggestsecuritydangerarea.Therefore,itiSnecessarytolow.1eveldesorptioncharacteristicsofcoalin—depthstudy.

InordertostudytheCBMdesorptioncharacteristicsoflowrankcoal,shouldbestudyreservoircharacteristicsfirst.Experimentmainlyincludescoal

typesindustryanalysis,coalrockofcomponents,porositydetermination,scanningelectronmicroscope,mercuryinjectionexperiments(pore

experiment(specificstructureandporecharacteristic),theliquidnitrogenadsorptioncharacteristic),theisothermaladsorptionsurfaceareaandporevolume

experiments.Thenwehavetoanalyzetheexperimentaldataanddotheisothermaldesorptionexperimentandvariabletemperaturedesorptionexperiment,analyzelawsofdesorptionmathematicalmodel.ThisiSthebasic

Throughtheexperimentstoandfurtherstudycharacteristicsofdiffusionandseepage.authorsummarizedtheconclusion.Theporeandanalysis,the

oflowrankcoalismainlyconstitutebybigpore

reflectsemi?closedporeandfineandsecondarypore.Poreformsoverallbottleneckpore,partlyreflectthecharacteristicsofsemi-closedpore.SurfaceiSmainlydistributedinthe5-6nm

abilityoflowrankcoaloverallbelowthemediumrankand50~60nm.Theadsorptionadsorptionandhigtlrankcoal,andthe

aabilityoflignitebelowlong—flamecoal.WbibuUfunctionisfittingfunctionforthe

adsorptioncurvefittingoflowrankcoal.TheCBMdesorptionrateoflowrankcoalishigher

fittingdegreeofthanthemediumrankandhighrankcoal.ThecurveWeibullfunctionisthe

highestforlowrankcoaldesorption.Finally,thepaperanalyzesandsummarizestheCBMadsorption/desorptioninfluencingfactorsofthelowrankcoal.

Keywords:LowrankcoalAdsorptionDesorptionWeibullfunction

Thesis:TheoreticalResearch


  本文关键词:低阶煤孔隙特征与解吸规律研究,由笔耕文化传播整理发布。



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