化学振荡反应调控的动态可逆智能体系

发布时间：2018-01-30 18:43

本文关键词： 化学振荡反应动态可逆作用动态共价键主-客体作用配位作用离子相互作用　出处：《化学进展》2017年07期 　论文类型：期刊论文

【摘要】：动态可逆作用是构筑智能材料体系,实现材料性能可控、可调性的重要工具。但是,多数基于动态可逆作用的智能体系仅能对"开/关"转换的外界刺激因素,如光、热、溶剂、pH等产生响应,不能实现自动调控。化学振荡反应及自振荡高分子材料的发展为新型自调控智能体系的构建提供了重要的思路。本文结合自调控智能体系的最新研究进展,介绍化学振荡反应调控的动态可逆智能体系(DRIS),包括利用动态共价键、主-客体作用、配位作用、离子作用、分子间作用等动态可逆作用构筑的纳米粒子自动聚集/分散体系、两亲性分子自组装/解组装体系、宏观凝胶自组装/解组装体系、自动分子器件、自动荧光振荡体系等。最后,对化学振荡反应调控的动态可逆智能体系的研究与发展进行展望。
[Abstract]:Dynamic reversible action is an important tool to construct intelligent material system and realize controllable and adjustable properties of material. However, most intelligent systems based on dynamic reversible action can only stimulate the external factors of "on / off" conversion. Such as light, heat, solvent pH and so on to produce the response. The development of chemical oscillating reaction and self-oscillating polymer materials provides an important way of thinking for the construction of new self-regulating intelligent system. This paper combines the latest research progress of self-regulated intelligent system. A dynamic reversible intelligent system for the regulation of chemical oscillatory reactions is introduced, including the use of dynamic covalent bonds, host-guest interactions, coordination actions and ionic interactions. Automatic aggregation / dispersion system of nanoparticles, amphiphilic molecular self-assembly / unassembly system, macro-gel self-assembly / de-assembly system, automatic molecular devices. Finally, the research and development of dynamic reversible intelligent systems controlled by chemical oscillations are prospected.
【作者单位】：西安工业大学材料与化工学院;
【基金】：国家自然科学基金青年基金项目(No.51603164) 陕西省自然科学基础研究计划项目(No.2016JQ5036) 西安工业大学校长基金项目(No.XAGDXJJ16010) 陕西省高校科协青年人才托举计划资助~~
【分类号】：O631;TB381
【正文快照】： The work was supported by the National Natural Science Foundation of China(No.51603164),the Natural Science Basic Research Plan in ShaanxiProvince of China(No.2016JQ5036),the President Foundation of Xi’an Technological University(No.XAGDXJJ16010)and the

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