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碱性固体燃料电池碱性聚合物电解质膜的最新研究进展

发布时间:2019-01-16 08:52
【摘要】:最近,碱性聚合物电解质膜燃料电池(APEMFC)因具有电极反应动力学快以及不依赖于贵金属铂催化剂等诸多优点而成为一个热门话题.作为其中一个关键部件,碱性聚合物电解质膜直接影响燃料电池的性能和成本.然而,迄今为止,仍然没有令人满意的碱性电解质膜材料.为此,大量研究被开展和报道.本文综述了近三年内文献中关于燃料电池碱性聚合物电解质膜的最新研究进展:包括各种各样的合成策略,构效关系,水管理以及非原位或原位稳定性测试等等.尤其是一些新的金属离子基阴离子交换膜和冠醚基阴离子交换膜首次被提及和评论.此外,还进一步预测了将来的发展趋势.
[Abstract]:Recently, alkaline polymer electrolyte membrane fuel cell (APEMFC) has become a hot topic because of its advantages of fast electrode reaction kinetics and no dependence on noble metal platinum catalyst. As one of the key components, alkaline polymer electrolyte membrane directly affects the performance and cost of fuel cells. So far, however, there is still no satisfactory alkaline electrolyte membrane material. To this end, a large number of studies have been carried out and reported. In this paper, the latest research progress on basic polymer electrolyte membranes for fuel cells in recent three years is reviewed, including various synthesis strategies, structure-activity relationships, water management and non-in-situ or in-situ stability tests, etc. In particular, some new metal ion-base anion exchange membranes and crown ether based anion exchange membranes have been mentioned and reviewed for the first time. In addition, the future development trend is further predicted.
【作者单位】: 昆明理工大学材料科学与工程学院;
【基金】:supported by the National Natural Science Foundation of China (51363011) the 46th Scientific Research Foundation for the Returned Overseas Chinese Scholars, Ministry of Education, China (6488-20130039) Program of High-level Introduced Talent of Yunnan Provincein 2012, China (10978125) Yunnan Project of Training Talent, China (1418425) Project of Key Discipline, China (14078232)~~
【分类号】:O646;TM911.4

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