N-杂环卡宾铂配合物的合成及其在有机反应中的应用

发布时间：2018-06-28 14:33

本文选题：N-杂环卡宾铂 + 催化　；参考：《化学进展》2017年04期

【摘要】：N-杂环卡宾铂配合物作为催化剂广泛应用于诸多有机催化反应,表现出优良的催化性能及稳定的物理、化学性质,在一定程度上解决了传统催化剂使用过程中遇到的稳定性难题,是有机金属催化化学的研究热点之一。本文介绍了近年来N-杂环卡宾铂配合物的合成及其作为催化剂在不饱和化合物(烯烃、炔烃和酮等)硅氢加成反应、烯炔环异构化反应、烯烃氢胺化、烯烃硼化反应和炔烃水化反应等有机反应中的应用研究新成果和进展,分析了N-杂环卡宾铂配合物作为催化剂的催化机理和存在的不足,并对N-杂环卡宾铂配合物作为催化剂的应用前景进行了展望。
[Abstract]:As catalysts, N-heterocyclic carbene platinum complexes have been widely used in many organic catalytic reactions, showing excellent catalytic performance and stable physical and chemical properties. To some extent, it solves the problem of stability encountered in the use of traditional catalysts, and is one of the research hotspots in organometallic catalytic chemistry. In this paper, the synthesis of N-heterocyclic carbene platinum complex and its catalytic effect on hydrosilylation of unsaturated compounds (alkenes, alkynes, ketones, etc.), isomerization of alkyne ring, hydroamination of olefins, etc. New achievements and advances in the application of organic reactions such as alkenes boronation and alkynes hydration have been made. The catalytic mechanism and shortcomings of N-heterocyclic carbene platinum complexes as catalysts have been analyzed. The application prospect of N-heterocyclic carbene platinum complex as catalyst was also prospected.
【作者单位】：杭州师范大学有机硅化学及材料技术教育部重点实验室;
【基金】：国家自然科学基金项目(No.21303034) 浙江省自然科学基金项目(No.LY14B030032)资助~~
【分类号】：O641.4

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