吩嗪衍生物在分子识别与自组装中的应用进展
发布时间：2018-11-11 13:57
【摘要】：种类繁多的吩嗪类化合物对有机化学研究者来说并不陌生,它广泛地存在于有机天然产物中并且具有较好的生物活性,含有天然骨架的吩嗪类化合物的合成过程简单,分子结构的功能化容易.该类化合物具有多个配位点和较大的共轭体系,使其容易形成氢键、离子键以及π-π堆积作用等弱相互作用.因此,吩嗪类化合物在超分子化学中的应用极为广泛.分子识别(MR)和超分子自组装(MS-A)是一直以来是超分子化学的两大重要的研究方向,综述了近几年来吩嗪衍生物在MR和MS-A中的应用进展.根据与吩嗪衍生物所作用的客体的类型的不同将MR分为阳离子识别(CR)、阴离子识别(AR)以及中性分子识别(NMR)三类.根据诱导因素的不同又将MS-A分为以下五类:氢键作用诱导的自组装(HBSA)、堆积作用诱导的自组装(ASA)、金属-配体作用诱导的自组装(M-LSA)、多种作用力协同作用诱导的自组装(MFSA)以及外界环境的导向作用诱导的自组装(OESA).
[Abstract]:Many kinds of phenazine compounds are not unfamiliar to organic chemistry researchers. They widely exist in organic natural products and have good biological activity. The synthesis process of phenazine compounds containing natural skeleton is simple. It is easy to functionalize the molecular structure. These compounds have many coordination points and large conjugated systems, which make them easy to form hydrogen bonds, ionic bonds and 蟺-蟺 stacking interactions. Therefore, phenazine compounds are widely used in supramolecular chemistry. Molecular recognition (MR) and supramolecular self-assembly (MS-A) are two important research directions in supramolecular chemistry. The applications of phenazine derivatives in MR and MS-A in recent years are reviewed. MR is classified into cationic (CR), anion recognition (AR) and neutral molecular recognition (NMR) according to the different types of guest interacting with phenazine derivatives. According to the different inducing factors, MS-A can be divided into the following five categories: Self-assembled (HBSA), piling induced by hydrogen bonding, self-assembled (ASA), metal-ligand interaction induced self-assembly (M-LSA). Self-assembled (MFSA) induced by synergistic action of multiple forces and self-assembled (OESA). Induced by guidance of external environment
【作者单位】： 西北师范大学化学化工学院生态环境相关高分子材料教育部重点实验室甘肃省高分子材料重点实验室;
【基金】：国家自然科学基金(Nos.21662031,21661018,21574104,21262032)资助项目~~
【分类号】：O641.3
[Abstract]:Many kinds of phenazine compounds are not unfamiliar to organic chemistry researchers. They widely exist in organic natural products and have good biological activity. The synthesis process of phenazine compounds containing natural skeleton is simple. It is easy to functionalize the molecular structure. These compounds have many coordination points and large conjugated systems, which make them easy to form hydrogen bonds, ionic bonds and 蟺-蟺 stacking interactions. Therefore, phenazine compounds are widely used in supramolecular chemistry. Molecular recognition (MR) and supramolecular self-assembly (MS-A) are two important research directions in supramolecular chemistry. The applications of phenazine derivatives in MR and MS-A in recent years are reviewed. MR is classified into cationic (CR), anion recognition (AR) and neutral molecular recognition (NMR) according to the different types of guest interacting with phenazine derivatives. According to the different inducing factors, MS-A can be divided into the following five categories: Self-assembled (HBSA), piling induced by hydrogen bonding, self-assembled (ASA), metal-ligand interaction induced self-assembly (M-LSA). Self-assembled (MFSA) induced by synergistic action of multiple forces and self-assembled (OESA). Induced by guidance of external environment
【作者单位】： 西北师范大学化学化工学院生态环境相关高分子材料教育部重点实验室甘肃省高分子材料重点实验室;
【基金】：国家自然科学基金(Nos.21662031,21661018,21574104,21262032)资助项目~~
【分类号】：O641.3
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