3,6-二(N-咪唑/苯并咪唑基)哒嗪配体配合物的合成、结构、荧光及光催化性能(英文)
发布时间:2021-04-02 22:31
用溶剂热法设计、合成了4个金属-有机配合物[Mn(L1)4(OH)2](1),{[MnL1(H2O)4]SO4}n(2),[CdL2(NO3)2]n(3)和{[Co(L2)2](PF6)2}n(4),(L1=3,6-二(N-咪唑基)哒嗪,L2=3,6-二(N-苯并咪唑基)哒嗪),并通过元素分析、红外、X射线单晶衍射对配合物结构进行了表征,测试结果表明配合物1具有单核结构,2为一维链结构,配合物3和4均为二维网状结构。此外,对配合物3和4的固态荧光性能及光催化的性能做了进一步研究。
【文章来源】:无机化学学报. 2016,32(05)北大核心SCICSCD
【文章页数】:9 页
【文章目录】:
0 Introduction
1 Experimental
1.1 Materials and general methods
1.2 Synthesis of ligand L1
1.3 Synthesis of ligand L2
1.4 Synthesis of complex 1
1.5 Synthesis of complex 2
1.6 Synthesis of complex 3
1.7 Synthesis of complex 4
1.8 Determination of photocatalytic activity
1.9 Structure determination
2 Results and discussion
2.1 Structure description of 1
2.2 Structure description of 2
2.3 Structure description of 3
2.4 Structure description of 4
2.5 Thermogravimetric analysis
2.6 XRPD patterns
2.7 Luminescent properties
2.8 Photocatalytic activity
3 Conclusions
本文编号:3116080
【文章来源】:无机化学学报. 2016,32(05)北大核心SCICSCD
【文章页数】:9 页
【文章目录】:
0 Introduction
1 Experimental
1.1 Materials and general methods
1.2 Synthesis of ligand L1
1.3 Synthesis of ligand L2
1.4 Synthesis of complex 1
1.5 Synthesis of complex 2
1.6 Synthesis of complex 3
1.7 Synthesis of complex 4
1.8 Determination of photocatalytic activity
1.9 Structure determination
2 Results and discussion
2.1 Structure description of 1
2.2 Structure description of 2
2.3 Structure description of 3
2.4 Structure description of 4
2.5 Thermogravimetric analysis
2.6 XRPD patterns
2.7 Luminescent properties
2.8 Photocatalytic activity
3 Conclusions
本文编号:3116080
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