吡唑-3-甲酸Cu(Ⅱ)/Mn(Ⅱ)配合物的合成、表征及常压下对二氧化碳催化转化(英文)
发布时间:2021-08-04 01:44
合成和表征了2个吡唑-3-甲酸过渡金属配合物[Cu2(pca)2(H2O)6]·2H2O(1),[Mn(Hpca)2(phen)]·3H2O(2)(H2pca=吡唑-3-甲酸;phen=菲咯啉)。X射线单晶衍射分析结果表明,配合物1属于单斜晶系P21/n空间群,它是一个畸变八面体的双核铜配合物;配合物2是一个畸变八面体的单核锰配合物。配合物1和2分别通过分子间的O-H…O,N-H…O氢键形成了三维网状结构。配合物1在二氧化碳的环加成反应中显示出了良好的催化效率(转化率高达97.4%;选择性高达98.9%)。
【文章来源】:无机化学学报. 2017,33(12)北大核心SCICSCD
【文章页数】:8 页
【文章目录】:
0 Introduction
1 Experimental
1.1 General methods and materials
1.2 Synthesis
1.3 Catalytic conversion of CO2to cyclic carbonate
1.4 X-ray crystallography
2 Results and discussion
2.1 Structure description
2.2 Catalytic conversion CO2to cyclic carbonate catalyzed by complexes 1 and 2
3 Conclusions
本文编号:3320742
【文章来源】:无机化学学报. 2017,33(12)北大核心SCICSCD
【文章页数】:8 页
【文章目录】:
0 Introduction
1 Experimental
1.1 General methods and materials
1.2 Synthesis
1.3 Catalytic conversion of CO2to cyclic carbonate
1.4 X-ray crystallography
2 Results and discussion
2.1 Structure description
2.2 Catalytic conversion CO2to cyclic carbonate catalyzed by complexes 1 and 2
3 Conclusions
本文编号:3320742
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