Hydrothermal Syntheses,Structure Characteristics and Magneti
发布时间：2021-07-12 17:45
Three new polyoxometalates K2[H2（As3O3）2(Mo6O18)（NiO6）]×H2O（1）, K2[H2-（As3O3）2(Mo6O18)（Co O6）]×H2O（2） and [Zn（H4,4?-bpy）2（H2O）4][（As3O3）2(Mo6O18)（ZnO6）]×4H2O（3）（4,4?-bpy = 4,4?-bipyridine） have been synthesized under hydrothermal conditions and characterized by IR, ele...
【文章来源】：结构化学. 2017,36(07)SCICSCD
【文章页数】：9 页
【文章目录】：
1 INTRODUCTION
2 EXPERIMENTAL
2.1 General considerations
2.2 Synthesis
2.2.1 Synthesis ofK2[H2 (As3O3) 2 (Mo6O18) (Ni O6) ]#H2O (1)
2.2.2 Synthesis ofK2[H2 (As3O3) 2 (Mo6O18) (Co O6) ]#H2O (2)
2.2.3 Synthesis of[Zn (H4, 4#-bipy) 2 (H2O) 4][ (As3O3) 2 (Mo6O18) (Zn O6) ]#4H2O (3)
2.3 Structure determination
3 RESULTS AND DISCUSSION
3.1 Syntheses
3.2 Structure description
3.2.1 Crystal structure of compound 1
3.2.2 Crystal structure of compound 2
3.2.3 Crystal structure of compound 3
3.3 FT-IR spectroscopy and X-ray photoelectron spectrum (XPS)
3.4 Magnetic properties
4 CONCLUSION
本文编号：3280367
【文章来源】：结构化学. 2017,36(07)SCICSCD
【文章页数】：9 页
【文章目录】：
1 INTRODUCTION
2 EXPERIMENTAL
2.1 General considerations
2.2 Synthesis
2.2.1 Synthesis ofK2[H2 (As3O3) 2 (Mo6O18) (Ni O6) ]#H2O (1)
2.2.2 Synthesis ofK2[H2 (As3O3) 2 (Mo6O18) (Co O6) ]#H2O (2)
2.2.3 Synthesis of[Zn (H4, 4#-bipy) 2 (H2O) 4][ (As3O3) 2 (Mo6O18) (Zn O6) ]#4H2O (3)
2.3 Structure determination
3 RESULTS AND DISCUSSION
3.1 Syntheses
3.2 Structure description
3.2.1 Crystal structure of compound 1
3.2.2 Crystal structure of compound 2
3.2.3 Crystal structure of compound 3
3.3 FT-IR spectroscopy and X-ray photoelectron spectrum (XPS)
3.4 Magnetic properties
4 CONCLUSION
本文编号：3280367
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