西藏拉抗俄斑岩铜钼矿床黑云母矿物化学特征
发布时间:2018-05-04 22:40
本文选题:斑岩铜钼矿床 + 拉抗俄 ; 参考:《地学前缘》2017年05期
【摘要】:西藏冈底斯成矿带拉抗俄斑岩铜钼矿床位于西藏特提斯构造域拉萨地块东段中南部。拉抗俄斑岩铜钼矿床黑云母分为岩浆黑云母和热液黑云母。岩浆黑云母和绢英岩化带的热液黑云母属于镁质黑云母,钾化带的热液黑云母属于镁质黑云母和金云母,具有富镁的特征,是斑岩铜多金属矿床的一个典型特征。成矿岩体花岗闪长斑岩,属于造山带钙碱性岩系,具壳幔混源的成因特点,并且其黑云母与角闪石共生。与钾化带和绢英岩化带的热液黑云母相比,岩浆黑云母具有较高的BaO和TiO2含量。与岩浆黑云母和绢英岩化带热液黑云母相比,钾化带热液黑云母具高Si和Mg(XMg),低Fe;而绢英岩化带的热液黑云母又比岩浆黑云母较高Mg(XMg)。岩浆黑云母温度为706~746℃,平均值725℃;钾化带热液黑云母温度为396~453℃,平均值422℃;绢英岩化带热液黑云母278~372℃,平均值331℃。拉抗俄矿床黑云母氧逸度较高,均为NNO,有利于铜钼矿化形成;从岩浆黑云母到钾化带热液黑云母氧逸度升高,有利于铜钼成矿物质的运移,而从钾化带热液黑云母到绢英岩化带热液黑云母氧逸度降低,温度和氧逸度的变化可能是铜钼沉淀的一个原因。岩浆黑云母和绢英岩化带热液黑云母遵循"F-Fe avoidance"结晶化学规则,而钾化带热液黑云母F与XMg不遵循"F-Fe avoidance"结晶化学规则。岩浆黑云母、钾化带和绢英岩化带热液黑云母Cl与XMg均不遵循"Mg-Cl avoidance"结晶化学规则。黑云母化学成分记录了岩浆结晶过程中流体成分的变化。从岩浆黑云母到钾化带热液黑云母,再到绢英岩化热液黑云母,Ⅳ(F)和Ⅳ(F/Cl)逐渐减小,Ⅳ(Cl)逐渐增大。岩浆向热液演化过程中,F和Cl含量不断增加。岩浆-成矿热液F和Cl的含量的变化,对成矿物质运移和沉淀具有重要的作用。从岩浆黑云母到钾化带热液黑云母,再到绢英岩化带热液黑云母,lg(fHF/fHCl)逐渐减小,lg(fH2O/fHCl)和lg(fH2O/fHF)逐渐增大。岩浆熔体和热液流体存在很大差别;并且绢英岩化热液流体与钾化热液流体也不同,黑云母卤素化学也不代表一种单一的流体;绢英岩化热液流体混合大气水。本文研究结果显示,黑云母化学成分可以反映岩浆的性质和化学成分以及结晶过程中的物理化学条件。
[Abstract]:The Lakon Russian porphyry copper-molybdenum deposit in the Gangdis metallogenic belt, Tibet, is located in the central and southern part of the eastern Lhasa block in the Tethys tectonic domain, Tibet. Biotite from the copper molybdenum deposit of Lakon porphyry is divided into magmatic biotite and hydrothermal biotite. The hydrothermal biotite of magmatic biotite and sericite zone belongs to magnesia biotite, and the hydrothermal biotite of potash zone belongs to magnesia biotite and phlogopite, which is a typical feature of porphyry copper polymetallic deposit. The granodiorite porphyry belongs to calc-alkaline series of orogenic belt and has genetic characteristics of crust-mantle mixing and its biotite and hornblende are symbiotic. The magmatic biotite has higher BaO and TiO2 contents than the hydrothermal biotite in the potash zone and sericite zone. Compared with the magmatic biotite and sericite zone, the hydrothermal biotite in the potash zone is characterized by high Si and MgO XMgO and low Fe, while the hydrothermal biotite in the sericite zone is higher than that in the magmatic biotite zone. The temperature of magmatic biotite is 706 ~ 746 鈩,
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