高活性低膨胀生物微晶玻璃的制备与性能表征
发布时间：2018-10-21 14:28
【摘要】：在钛合金表面制备生物活性涂层已成为种植体材料研究的一个重点,制备出适用于钛合金表面具有骨诱导或骨引导作用的生物活性涂层材料在种植体的研制中具有重要的地位。本文以典型的Na2O-CaO-SiO2-P2O5系45S5生物玻璃组分为基础,分别以6mol%的K2O、MgO、B2O3、TiO2、CaF2、NH4HF26种成分替代45S5中6mol%CaO,并采用溶胶凝胶法制备出了7种生物微晶玻璃,探索具有良好生物活性并与钛合金在性能上特别是热膨胀系数相匹配的新型涂层材料。采用X射线衍射(XRD)、扫描电镜(SEM)、傅立叶红外转换光谱(FTIR)、热膨胀系数测试仪、显微硬度计、电子拉伸试验机等测试方法对所制备的生物活性微晶玻璃材料的组织结构及物理性能进行系统的研究,并对材料在模拟体液中的生物活性进行了表征。 由溶胶凝胶法制备的7种不同组分的玻璃粉末的DTA曲线分析可知,7种不同成分的生物玻璃在710℃和850℃附近基本上都会出现放热析晶峰,说明通过适当的热处理工艺可以实现玻璃的晶化转变。并由此确定玻璃粉末的微晶化处理为在710℃时保温2h后再升温至850℃时保温1h。 溶胶凝胶法制备的7种不同组分的玻璃粉末以非晶相为主。晶化处理后,7种玻璃均有结晶相析出,结晶相主要有以Na6Ca3Si6O18为主的NaxCa6-0.5xSi6O18晶相和少量Na2CaSi3O8晶相,其SEM表面形貌中可观察到颗粒状、块状以及条状的细小晶粒的存在,K2O、B2O3(?)CaF2的添加可增加玻璃试样的致密度。在45S5玻璃组分的基础上,除MgO外其它物质的添加都降低了45S5的析晶温度,促进了45S5析晶,以B203和CaF2的促进作用最为明显。 各种组分的添加有助于生物微晶玻璃抗弯强度、硬度的提高和断裂韧度的降低。特别地,CaF2的引入对基础玻璃抗弯强度和硬度的提高最为明显。在弹性模量方面,只有MgO的添加可以较大程度的提高生物微晶玻璃的弹性模量值,其它组分的引入则影响较小。7种成分的生物微晶玻璃20～500℃的线膨胀系数大致在(9.1～12.5)×10-6/℃范围之内,符合钛合金涂层材料线膨胀系数较低的要求。综合各物理性能指标进行评估,引入CaF2组分的微晶玻璃物理性能最好。比较适合用作钛合金表面涂层材料。 7种生物微晶玻璃在模拟体液中浸泡2d后表面均有沉积相出现,经过EDS、XRD和FTIR分析发现表面沉积相主要为碳酸磷灰石以及少量的羟基磷灰石。N6试样浸泡14d表面基本被磷灰石覆盖,21d后已经生成了较厚的一层磷灰石。溶胶凝胶法制备的所有试样均具有良好的生物活性,但是N3试样生物活性较其他试样低。 综合物理性能及生物活性等方面考虑,引入6mol%CaF2的生物活性微晶玻璃具有较好的物理性能及良好的生物活性,并且线膨胀系数与钛合金接近,适合作为钛合金表面涂层材料。
[Abstract]:%E5%9C%A8%E9%92%9B%E5%90%88%E9%87%91%E8%A1%A8%E9%9D%A2%E5%88%B6%E5%A4%87%E7%94%9F%E7%89%A9%E6%B4%BB%E6%80%A7%E6%B6%82%E5%B1%82%E5%B7%B2%E6%88%90%E4%B8%BA%E7%A7%8D%E6%A4%8D%E4%BD%93%E6%9D%90%E6%96%99%E7%A0%94%E7%A9%B6%E7%9A%84%E4%B8%80%E4%B8%AA%E9%87%8D%E7%82%B9%2C%E5%88%B6%E5%A4%87%E5%87%BA%E9%80%82%E7%94%A8%E4%BA%8E%E9%92%9B%E5%90%88%E9%87%91%E8%A1%A8%E9%9D%A2%E5%85%B7%E6%9C%89%E9%AA%A8%E8%AF%B1%E5%AF%BC%E6%88%96%E9%AA%A8%E5%BC%95%E5%AF%BC%E4%BD%9C%E7%94%A8%E7%9A%84%E7%94%9F%E7%89%A9%E6%B4%BB%E6%80%A7%E6%B6%82%E5%B1%82%E6%9D%90%E6%96%99%E5%9C%A8%E7%A7%8D%E6%A4%8D%E4%BD%93%E7%9A%84%E7%A0%94%E5%88%B6%E4%B8%AD%E5%85%B7%E6%9C%89%E9%87%8D%E8%A6%81%E7%9A%84%E5%9C%B0%E4%BD%8D.%E6%9C%AC%E6%96%87%E4%BB%A5%E5%85%B8%E5%9E%8B%E7%9A%84Na2O-CaO-SiO2-P2O5%E7%B3%BB45S5%E7%94%9F%E7%89%A9%E7%8E%BB%E7%92%83%E7%BB%84%E5%88%86%E4%B8%BA%E5%9F%BA%E7%A1%80%2C%E5%88%86%E5%88%AB%E4%BB%A56mol%25%E7%9A%84K2O%2CMgO%2CB2O3%2CTiO2%2CCaF2%2CNH4HF26%E7%A7%8D%E6%88%90%E5%88%86%E6%9B%BF%E4%BB%A345S5%E4%B8%AD6mol%CAO%2C%E5%B9%B6%E9%87%87%E7%94%A8%E6%BA%B6%E8%83%B6%E5%87%9D%E8%83%B6%E6%B3%95%E5%88%B6%E5%A4%87%E5%87%BA%E4%BA%867%E7%A7%8D%E7%94%9F%E7%89%A9%E5%BE%AE%E6%99%B6%E7%8E%BB%E7%92%83%2C%E6%8E%A2%E7%B4%A2%E5%85%B7%E6%9C%89%E8%89%AF%E5%A5%BD%E7%94%9F%E7%89%A9%E6%B4%BB%E6%80%A7%E5%B9%B6%E4%B8%8E%E9%92%9B%E5%90%88%E9%87%91%E5%9C%A8%E6%80%A7%E8%83%BD%E4%B8%8A%E7%89%B9%E5%88%AB%E6%98%AF%E7%83%AD%E8%86%A8%E8%83%80%E7%B3%BB%E6%95%B0%E7%9B%B8%E5%8C%B9%E9%85%8D%E7%9A%84%E6%96%B0%E5%9E%8B%E6%B6%82%E5%B1%82%E6%9D%90%E6%96%99.%E9%87%87%E7%94%A8X%E5%B0%84%E7%BA%BF%E8%A1%8D%E5%B0%84%28XRD%29%2C%E6%89%AB%E6%8F%8F%E7%94%B5%E9%95%9C%28SEM%29%2C%E5%82%85%E7%AB%8B%E5%8F%B6%E7%BA%A2%E5%A4%96%E8%BD%AC%E6%8D%A2%E5%85%89%E8%B0%B1%28FTIR%29%2C%E7%83%AD%E8%86%A8%E8%83%80%E7%B3%BB%E6%95%B0%E6%B5%8B%E8%AF%95%E4%BB%AA%2C%E6%98%BE%E5%BE%AE%E7%A1%AC%E5%BA%A6%E8%AE%A1%2C%E7%94%B5%E5%AD%90%E6%8B%89%E4%BC%B8%E8%AF%95%E9%AA%8C%E6%9C%BA%E7%AD%89%E6%B5%8B%E8%AF%95%E6%96%B9%E6%B3%95%E5%AF%B9%E6%89%80%E5%88%B6%E5%A4%87%E7%9A%84%E7%94%9F%E7%89%A9%E6%B4%BB%E6%80%A7%E5%BE%AE%E6%99%B6%E7%8E%BB%E7%92%83%E6%9D%90%E6%96%99%E7%9A%84%E7%BB%84%E7%BB%87%E7%BB%93%E6%9E%84%E5%8F%8A%E7%89%A9%E7%90%86%E6%80%A7%E8%83%BD%E8%BF%9B%E8%A1%8C%E7%B3%BB%E7%BB%9F%E7%9A%84%E7%A0%94%E7%A9%B6%2C%E5%B9%B6%E5%AF%B9%E6%9D%90%E6%96%99%E5%9C%A8%E6%A8%A1%E6%8B%9F%E4%BD%93%E6%B6%B2%E4%B8%AD%E7%9A%84%E7%94%9F%E7%89%A9%E6%B4%BB%E6%80%A7%E8%BF%9B%E8%A1%8C%E4%BA%86%E8%A1%A8%E5%BE%81.%0D%0A%0D%0A%09%E7%94%B1%E6%BA%B6%E8%83%B6%E5%87%9D%E8%83%B6%E6%B3%95%E5%88%B6%E5%A4%87%E7%9A%847%E7%A7%8D%E4%B8%8D%E5%90%8C%E7%BB%84%E5%88%86%E7%9A%84%E7%8E%BB%E7%92%83%E7%B2%89%E6%9C%AB%E7%9A%84DTA%E6%9B%B2%E7%BA%BF%E5%88%86%E6%9E%90%E5%8F%AF%E7%9F%A5%2C7%E7%A7%8D%E4%B8%8D%E5%90%8C%E6%88%90%E5%88%86%E7%9A%84%E7%94%9F%E7%89%A9%E7%8E%BB%E7%92%83%E5%9C%A8710%E2%84%83%E5%92%8C850%E2%84%83%E9%99%84%E8%BF%91%E5%9F%BA%E6%9C%AC%E4%B8%8A%E9%83%BD%E4%BC%9A%E5%87%BA%E7%8E%B0%E6%94%BE%E7%83%AD%E6%9E%90%E6%99%B6%E5%B3%B0%2C%E8%AF%B4%E6%98%8E%E9%80%9A%E8%BF%87%E9%80%82%E5%BD%93%E7%9A%84%E7%83%AD%E5%A4%84%E7%90%86%E5%B7%A5%E8%89%BA%E5%8F%AF%E4%BB%A5%E5%AE%9E%E7%8E%B0%E7%8E%BB%E7%92%83%E7%9A%84%E6%99%B6%E5%8C%96%E8%BD%AC%E5%8F%98.%E5%B9%B6%E7%94%B1%E6%AD%A4%E7%A1%AE%E5%AE%9A%E7%8E%BB%E7%92%83%E7%B2%89%E6%9C%AB%E7%9A%84%E5%BE%AE%E6%99%B6%E5%8C%96%E5%A4%84%E7%90%86%E4%B8%BA%E5%9C%A8710%E2%84%83%E6%97%B6%E4%BF%9D%E6%B8%A92h%E5%90%8E%E5%86%8D%E5%8D%87%E6%B8%A9%E8%87%B3850%E2%84%83%E6%97%B6%E4%BF%9D%E6%B8%A91h.%0D%0A%0D%0A%09%E6%BA%B6%E8%83%B6%E5%87%9D%E8%83%B6%E6%B3%95%E5%88%B6%E5%A4%87%E7%9A%847%E7%A7%8D%E4%B8%8D%E5%90%8C%E7%BB%84%E5%88%86%E7%9A%84%E7%8E%BB%E7%92%83%E7%B2%89%E6%9C%AB%E4%BB%A5%E9%9D%9E%E6%99%B6%E7%9B%B8%E4%B8%BA%E4%B8%BB.%E6%99%B6%E5%8C%96%E5%A4%84%E7%90%86%E5%90%8E%2C7%E7%A7%8D%E7%8E%BB%E7%92%83%E5%9D%87%E6%9C%89%E7%BB%93%E6%99%B6%E7%9B%B8%E6%9E%90%E5%87%BA%2C%E7%BB%93%E6%99%B6%E7%9B%B8%E4%B8%BB%E8%A6%81%E6%9C%89%E4%BB%A5Na6Ca3Si6O18%E4%B8%BA%E4%B8%BB%E7%9A%84NaxCa6-0.5xSi6O18%E6%99%B6%E7%9B%B8%E5%92%8C%E5%B0%91%E9%87%8FNa2CaSi3O8%E6%99%B6%E7%9B%B8%2C%E5%85%B6SEM%E8%A1%A8%E9%9D%A2%E5%BD%A2%E8%B2%8C%E4%B8%AD%E5%8F%AF%E8%A7%82%E5%AF%9F%E5%88%B0%E9%A2%97%E7%B2%92%E7%8A%B6%2C%E5%9D%97%E7%8A%B6%E4%BB%A5%E5%8F%8A%E6%9D%A1%E7%8A%B6%E7%9A%84%E7%BB%86%E5%B0%8F%E6%99%B6%E7%B2%92%E7%9A%84%E5%AD%98%E5%9C%A8%2CK2O%2CB2O3%28%3F%29CaF2%E7%9A%84%E6%B7%BB%E5%8A%A0%E5%8F%AF%E5%A2%9E%E5%8A%A0%E7%8E%BB%E7%92%83%E8%AF%95%E6%A0%B7%E7%9A%84%E8%87%B4%E5%AF%86%E5%BA%A6.%E5%9C%A845S5%E7%8E%BB%E7%92%83%E7%BB%84%E5%88%86%E7%9A%84%E5%9F%BA%E7%A1%80%E4%B8%8A%2C%E9%99%A4MgO%E5%A4%96%E5%85%B6%E5%AE%83%E7%89%A9%E8%B4%A8%E7%9A%84%E6%B7%BB%E5%8A%A0%E9%83%BD%E9%99%8D%E4%BD%8E%E4%BA%8645S5%E7%9A%84%E6%9E%90%E6%99%B6%E6%B8%A9%E5%BA%A6%2C%E4%BF%83%E8%BF%9B%E4%BA%8645S5%E6%9E%90%E6%99%B6%2C%E4%BB%A5B203%E5%92%8CCaF2%E7%9A%84%E4%BF%83%E8%BF%9B%E4%BD%9C%E7%94%A8%E6%9C%80%E4%B8%BA%E6%98%8E%E6%98%BE.%0D%0A%0D%0A%09%E5%90%84%E7%A7%8D%E7%BB%84%E5%88%86%E7%9A%84%E6%B7%BB%E5%8A%A0%E6%9C%89%E5%8A%A9%E4%BA%8E%E7%94%9F%E7%89%A9%E5%BE%AE%E6%99%B6%E7%8E%BB%E7%92%83%E6%8A%97%E5%BC%AF%E5%BC%BA%E5%BA%A6%2C%E7%A1%AC%E5%BA%A6%E7%9A%84%E6%8F%90%E9%AB%98%E5%92%8C%E6%96%AD%E8%A3%82%E9%9F%A7%E5%BA%A6%E7%9A%84%E9%99%8D%E4%BD%8E.%E7%89%B9%E5%88%AB%E5%9C%B0%2CCaF2%E7%9A%84%E5%BC%95%E5%85%A5%E5%AF%B9%E5%9F%BA%E7%A1%80%E7%8E%BB%E7%92%83%E6%8A%97%E5%BC%AF%E5%BC%BA%E5%BA%A6%E5%92%8C%E7%A1%AC%E5%BA%A6%E7%9A%84%E6%8F%90%E9%AB%98%E6%9C%80%E4%B8%BA%E6%98%8E%E6%98%BE.%E5%9C%A8%E5%BC%B9%E6%80%A7%E6%A8%A1%E9%87%8F%E6%96%B9%E9%9D%A2%2C%E5%8F%AA%E6%9C%89MgO%E7%9A%84%E6%B7%BB%E5%8A%A0%E5%8F%AF%E4%BB%A5%E8%BE%83%E5%A4%A7%E7%A8%8B%E5%BA%A6%E7%9A%84%E6%8F%90%E9%AB%98%E7%94%9F%E7%89%A9%E5%BE%AE%E6%99%B6%E7%8E%BB%E7%92%83%E7%9A%84%E5%BC%B9%E6%80%A7%E6%A8%A1%E9%87%8F%E5%80%BC%2C%E5%85%B6%E5%AE%83%E7%BB%84%E5%88%86%E7%9A%84%E5%BC%95%E5%85%A5%E5%88%99%E5%BD%B1%E5%93%8D%E8%BE%83%E5%B0%8F.7%E7%A7%8D%E6%88%90%E5%88%86%E7%9A%84%E7%94%9F%E7%89%A9%E5%BE%AE%E6%99%B6%E7%8E%BB%E7%92%8320%EF%BD%9E500%E2%84%83%E7%9A%84%E7%BA%BF%E8%86%A8%E8%83%80%E7%B3%BB%E6%95%B0%E5%A4%A7%E8%87%B4%E5%9C%A8%289.1%EF%BD%9E12.5%29%C3%9710-6%2F%E2%84%83%E8%8C%83%E5%9B%B4%E4%B9%8B%E5%86%85%2C%E7%AC%A6%E5%90%88%E9%92%9B%E5%90%88%E9%87%91%E6%B6%82%E5%B1%82%E6%9D%90%E6%96%99%E7%BA%BF%E8%86%A8%E8%83%80%E7%B3%BB%E6%95%B0%E8%BE%83%E4%BD%8E%E7%9A%84%E8%A6%81%E6%B1%82.%E7%BB%BC%E5%90%88%E5%90%84%E7%89%A9%E7%90%86%E6%80%A7%E8%83%BD%E6%8C%87%E6%A0%87%E8%BF%9B%E8%A1%8C%E8%AF%84%E4%BC%B0%2C%E5%BC%95%E5%85%A5CaF2%E7%BB%84%E5%88%86%E7%9A%84%E5%BE%AE%E6%99%B6%E7%8E%BB%E7%92%83%E7%89%A9%E7%90%86%E6%80%A7%E8%83%BD%E6%9C%80%E5%A5%BD.%E6%AF%94%E8%BE%83%E9%80%82%E5%90%88%E7%94%A8%E4%BD%9C%E9%92%9B%E5%90%88%E9%87%91%E8%A1%A8%E9%9D%A2%E6%B6%82%E5%B1%82%E6%9D%90%E6%96%99.%0D%0A%0D%0A%097%E7%A7%8D%E7%94%9F%E7%89%A9%E5%BE%AE%E6%99%B6%E7%8E%BB%E7%92%83%E5%9C%A8%E6%A8%A1%E6%8B%9F%E4%BD%93%E6%B6%B2%E4%B8%AD%E6%B5%B8%E6%B3%A12d%E5%90%8E%E8%A1%A8%E9%9D%A2%E5%9D%87%E6%9C%89%E6%B2%89%E7%A7%AF%E7%9B%B8%E5%87%BA%E7%8E%B0%2C%E7%BB%8F%E8%BF%87EDS%2CXRD%E5%92%8CFTIR%E5%88%86%E6%9E%90%E5%8F%91%E7%8E%B0%E8%A1%A8%E9%9D%A2%E6%B2%89%E7%A7%AF%E7%9B%B8%E4%B8%BB%E8%A6%81%E4%B8%BA%E7%A2%B3%E9%85%B8%E7%A3%B7%E7%81%B0%E7%9F%B3%E4%BB%A5%E5%8F%8A%E5%B0%91%E9%87%8F%E7%9A%84%E7%BE%9F%E5%9F%BA%E7%A3%B7%E7%81%B0%E7%9F%B3.N6%E8%AF%95%E6%A0%B7%E6%B5%B8%E6%B3%A114d%E8%A1%A8%E9%9D%A2%E5%9F%BA%E6%9C%AC%E8%A2%AB%E7%A3%B7%E7%81%B0%E7%9F%B3%E8%A6%86%E7%9B%96%2C21d%E5%90%8E%E5%B7%B2%E7%BB%8F%E7%94%9F%E6%88%90%E4%BA%86%E8%BE%83%E5%8E%9A%E7%9A%84%E4%B8%80%E5%B1%82%E7%A3%B7%E7%81%B0%E7%9F%B3.%E6%BA%B6%E8%83%B6%E5%87%9D%E8%83%B6%E6%B3%95%E5%88%B6%E5%A4%87%E7%9A%84%E6%89%80%E6%9C%89%E8%AF%95%E6%A0%B7%E5%9D%87%E5%85%B7%E6%9C%89%E8%89%AF%E5%A5%BD%E7%9A%84%E7%94%9F%E7%89%A9%E6%B4%BB%E6%80%A7%2C%E4%BD%86%E6%98%AFN3%E8%AF%95%E6%A0%B7%E7%94%9F%E7%89%A9%E6%B4%BB%E6%80%A7%E8%BE%83%E5%85%B6%E4%BB%96%E8%AF%95%E6%A0%B7%E4%BD%8E.%0D%0A%0D%0A%09%E7%BB%BC%E5%90%88%E7%89%A9%E7%90%86%E6%80%A7%E8%83%BD%E5%8F%8A%E7%94%9F%E7%89%A9%E6%B4%BB%E6%80%A7%E7%AD%89%E6%96%B9%E9%9D%A2%E8%80%83%E8%99%91%2C%E5%BC%95%E5%85%A56mol%CAF2%E7%9A%84%E7%94%9F%E7%89%A9%E6%B4%BB%E6%80%A7%E5%BE%AE%E6%99%B6%E7%8E%BB%E7%92%83%E5%85%B7%E6%9C%89%E8%BE%83%E5%A5%BD%E7%9A%84%E7%89%A9%E7%90%86%E6%80%A7%E8%83%BD%E5%8F%8A%E8%89%AF%E5%A5%BD%E7%9A%84%E7%94%9F%E7%89%A9%E6%B4%BB%E6%80%A7%2C%E5%B9%B6%E4%B8%94%E7%BA%BF%E8%86%A8%E8%83%80%E7%B3%BB%E6%95%B0%E4%B8%8E%E9%92%9B%E5%90%88%E9%87%91%E6%8E%A5%E8%BF%91%2C%E9%80%82%E5%90%88%E4%BD%9C%E4%B8%BA%E9%92%9B%E5%90%88%E9%87%91%E8%A1%A8%E9%9D%A2%E6%B6%82%E5%B1%82%E6%9D%90%E6%96%99.
【学位授予单位】：山东大学
【学位级别】：硕士
【学位授予年份】：2012
【分类号】：R318.08
本文编号：2285379
[Abstract]:%E5%9C%A8%E9%92%9B%E5%90%88%E9%87%91%E8%A1%A8%E9%9D%A2%E5%88%B6%E5%A4%87%E7%94%9F%E7%89%A9%E6%B4%BB%E6%80%A7%E6%B6%82%E5%B1%82%E5%B7%B2%E6%88%90%E4%B8%BA%E7%A7%8D%E6%A4%8D%E4%BD%93%E6%9D%90%E6%96%99%E7%A0%94%E7%A9%B6%E7%9A%84%E4%B8%80%E4%B8%AA%E9%87%8D%E7%82%B9%2C%E5%88%B6%E5%A4%87%E5%87%BA%E9%80%82%E7%94%A8%E4%BA%8E%E9%92%9B%E5%90%88%E9%87%91%E8%A1%A8%E9%9D%A2%E5%85%B7%E6%9C%89%E9%AA%A8%E8%AF%B1%E5%AF%BC%E6%88%96%E9%AA%A8%E5%BC%95%E5%AF%BC%E4%BD%9C%E7%94%A8%E7%9A%84%E7%94%9F%E7%89%A9%E6%B4%BB%E6%80%A7%E6%B6%82%E5%B1%82%E6%9D%90%E6%96%99%E5%9C%A8%E7%A7%8D%E6%A4%8D%E4%BD%93%E7%9A%84%E7%A0%94%E5%88%B6%E4%B8%AD%E5%85%B7%E6%9C%89%E9%87%8D%E8%A6%81%E7%9A%84%E5%9C%B0%E4%BD%8D.%E6%9C%AC%E6%96%87%E4%BB%A5%E5%85%B8%E5%9E%8B%E7%9A%84Na2O-CaO-SiO2-P2O5%E7%B3%BB45S5%E7%94%9F%E7%89%A9%E7%8E%BB%E7%92%83%E7%BB%84%E5%88%86%E4%B8%BA%E5%9F%BA%E7%A1%80%2C%E5%88%86%E5%88%AB%E4%BB%A56mol%25%E7%9A%84K2O%2CMgO%2CB2O3%2CTiO2%2CCaF2%2CNH4HF26%E7%A7%8D%E6%88%90%E5%88%86%E6%9B%BF%E4%BB%A345S5%E4%B8%AD6mol%CAO%2C%E5%B9%B6%E9%87%87%E7%94%A8%E6%BA%B6%E8%83%B6%E5%87%9D%E8%83%B6%E6%B3%95%E5%88%B6%E5%A4%87%E5%87%BA%E4%BA%867%E7%A7%8D%E7%94%9F%E7%89%A9%E5%BE%AE%E6%99%B6%E7%8E%BB%E7%92%83%2C%E6%8E%A2%E7%B4%A2%E5%85%B7%E6%9C%89%E8%89%AF%E5%A5%BD%E7%94%9F%E7%89%A9%E6%B4%BB%E6%80%A7%E5%B9%B6%E4%B8%8E%E9%92%9B%E5%90%88%E9%87%91%E5%9C%A8%E6%80%A7%E8%83%BD%E4%B8%8A%E7%89%B9%E5%88%AB%E6%98%AF%E7%83%AD%E8%86%A8%E8%83%80%E7%B3%BB%E6%95%B0%E7%9B%B8%E5%8C%B9%E9%85%8D%E7%9A%84%E6%96%B0%E5%9E%8B%E6%B6%82%E5%B1%82%E6%9D%90%E6%96%99.%E9%87%87%E7%94%A8X%E5%B0%84%E7%BA%BF%E8%A1%8D%E5%B0%84%28XRD%29%2C%E6%89%AB%E6%8F%8F%E7%94%B5%E9%95%9C%28SEM%29%2C%E5%82%85%E7%AB%8B%E5%8F%B6%E7%BA%A2%E5%A4%96%E8%BD%AC%E6%8D%A2%E5%85%89%E8%B0%B1%28FTIR%29%2C%E7%83%AD%E8%86%A8%E8%83%80%E7%B3%BB%E6%95%B0%E6%B5%8B%E8%AF%95%E4%BB%AA%2C%E6%98%BE%E5%BE%AE%E7%A1%AC%E5%BA%A6%E8%AE%A1%2C%E7%94%B5%E5%AD%90%E6%8B%89%E4%BC%B8%E8%AF%95%E9%AA%8C%E6%9C%BA%E7%AD%89%E6%B5%8B%E8%AF%95%E6%96%B9%E6%B3%95%E5%AF%B9%E6%89%80%E5%88%B6%E5%A4%87%E7%9A%84%E7%94%9F%E7%89%A9%E6%B4%BB%E6%80%A7%E5%BE%AE%E6%99%B6%E7%8E%BB%E7%92%83%E6%9D%90%E6%96%99%E7%9A%84%E7%BB%84%E7%BB%87%E7%BB%93%E6%9E%84%E5%8F%8A%E7%89%A9%E7%90%86%E6%80%A7%E8%83%BD%E8%BF%9B%E8%A1%8C%E7%B3%BB%E7%BB%9F%E7%9A%84%E7%A0%94%E7%A9%B6%2C%E5%B9%B6%E5%AF%B9%E6%9D%90%E6%96%99%E5%9C%A8%E6%A8%A1%E6%8B%9F%E4%BD%93%E6%B6%B2%E4%B8%AD%E7%9A%84%E7%94%9F%E7%89%A9%E6%B4%BB%E6%80%A7%E8%BF%9B%E8%A1%8C%E4%BA%86%E8%A1%A8%E5%BE%81.%0D%0A%0D%0A%09%E7%94%B1%E6%BA%B6%E8%83%B6%E5%87%9D%E8%83%B6%E6%B3%95%E5%88%B6%E5%A4%87%E7%9A%847%E7%A7%8D%E4%B8%8D%E5%90%8C%E7%BB%84%E5%88%86%E7%9A%84%E7%8E%BB%E7%92%83%E7%B2%89%E6%9C%AB%E7%9A%84DTA%E6%9B%B2%E7%BA%BF%E5%88%86%E6%9E%90%E5%8F%AF%E7%9F%A5%2C7%E7%A7%8D%E4%B8%8D%E5%90%8C%E6%88%90%E5%88%86%E7%9A%84%E7%94%9F%E7%89%A9%E7%8E%BB%E7%92%83%E5%9C%A8710%E2%84%83%E5%92%8C850%E2%84%83%E9%99%84%E8%BF%91%E5%9F%BA%E6%9C%AC%E4%B8%8A%E9%83%BD%E4%BC%9A%E5%87%BA%E7%8E%B0%E6%94%BE%E7%83%AD%E6%9E%90%E6%99%B6%E5%B3%B0%2C%E8%AF%B4%E6%98%8E%E9%80%9A%E8%BF%87%E9%80%82%E5%BD%93%E7%9A%84%E7%83%AD%E5%A4%84%E7%90%86%E5%B7%A5%E8%89%BA%E5%8F%AF%E4%BB%A5%E5%AE%9E%E7%8E%B0%E7%8E%BB%E7%92%83%E7%9A%84%E6%99%B6%E5%8C%96%E8%BD%AC%E5%8F%98.%E5%B9%B6%E7%94%B1%E6%AD%A4%E7%A1%AE%E5%AE%9A%E7%8E%BB%E7%92%83%E7%B2%89%E6%9C%AB%E7%9A%84%E5%BE%AE%E6%99%B6%E5%8C%96%E5%A4%84%E7%90%86%E4%B8%BA%E5%9C%A8710%E2%84%83%E6%97%B6%E4%BF%9D%E6%B8%A92h%E5%90%8E%E5%86%8D%E5%8D%87%E6%B8%A9%E8%87%B3850%E2%84%83%E6%97%B6%E4%BF%9D%E6%B8%A91h.%0D%0A%0D%0A%09%E6%BA%B6%E8%83%B6%E5%87%9D%E8%83%B6%E6%B3%95%E5%88%B6%E5%A4%87%E7%9A%847%E7%A7%8D%E4%B8%8D%E5%90%8C%E7%BB%84%E5%88%86%E7%9A%84%E7%8E%BB%E7%92%83%E7%B2%89%E6%9C%AB%E4%BB%A5%E9%9D%9E%E6%99%B6%E7%9B%B8%E4%B8%BA%E4%B8%BB.%E6%99%B6%E5%8C%96%E5%A4%84%E7%90%86%E5%90%8E%2C7%E7%A7%8D%E7%8E%BB%E7%92%83%E5%9D%87%E6%9C%89%E7%BB%93%E6%99%B6%E7%9B%B8%E6%9E%90%E5%87%BA%2C%E7%BB%93%E6%99%B6%E7%9B%B8%E4%B8%BB%E8%A6%81%E6%9C%89%E4%BB%A5Na6Ca3Si6O18%E4%B8%BA%E4%B8%BB%E7%9A%84NaxCa6-0.5xSi6O18%E6%99%B6%E7%9B%B8%E5%92%8C%E5%B0%91%E9%87%8FNa2CaSi3O8%E6%99%B6%E7%9B%B8%2C%E5%85%B6SEM%E8%A1%A8%E9%9D%A2%E5%BD%A2%E8%B2%8C%E4%B8%AD%E5%8F%AF%E8%A7%82%E5%AF%9F%E5%88%B0%E9%A2%97%E7%B2%92%E7%8A%B6%2C%E5%9D%97%E7%8A%B6%E4%BB%A5%E5%8F%8A%E6%9D%A1%E7%8A%B6%E7%9A%84%E7%BB%86%E5%B0%8F%E6%99%B6%E7%B2%92%E7%9A%84%E5%AD%98%E5%9C%A8%2CK2O%2CB2O3%28%3F%29CaF2%E7%9A%84%E6%B7%BB%E5%8A%A0%E5%8F%AF%E5%A2%9E%E5%8A%A0%E7%8E%BB%E7%92%83%E8%AF%95%E6%A0%B7%E7%9A%84%E8%87%B4%E5%AF%86%E5%BA%A6.%E5%9C%A845S5%E7%8E%BB%E7%92%83%E7%BB%84%E5%88%86%E7%9A%84%E5%9F%BA%E7%A1%80%E4%B8%8A%2C%E9%99%A4MgO%E5%A4%96%E5%85%B6%E5%AE%83%E7%89%A9%E8%B4%A8%E7%9A%84%E6%B7%BB%E5%8A%A0%E9%83%BD%E9%99%8D%E4%BD%8E%E4%BA%8645S5%E7%9A%84%E6%9E%90%E6%99%B6%E6%B8%A9%E5%BA%A6%2C%E4%BF%83%E8%BF%9B%E4%BA%8645S5%E6%9E%90%E6%99%B6%2C%E4%BB%A5B203%E5%92%8CCaF2%E7%9A%84%E4%BF%83%E8%BF%9B%E4%BD%9C%E7%94%A8%E6%9C%80%E4%B8%BA%E6%98%8E%E6%98%BE.%0D%0A%0D%0A%09%E5%90%84%E7%A7%8D%E7%BB%84%E5%88%86%E7%9A%84%E6%B7%BB%E5%8A%A0%E6%9C%89%E5%8A%A9%E4%BA%8E%E7%94%9F%E7%89%A9%E5%BE%AE%E6%99%B6%E7%8E%BB%E7%92%83%E6%8A%97%E5%BC%AF%E5%BC%BA%E5%BA%A6%2C%E7%A1%AC%E5%BA%A6%E7%9A%84%E6%8F%90%E9%AB%98%E5%92%8C%E6%96%AD%E8%A3%82%E9%9F%A7%E5%BA%A6%E7%9A%84%E9%99%8D%E4%BD%8E.%E7%89%B9%E5%88%AB%E5%9C%B0%2CCaF2%E7%9A%84%E5%BC%95%E5%85%A5%E5%AF%B9%E5%9F%BA%E7%A1%80%E7%8E%BB%E7%92%83%E6%8A%97%E5%BC%AF%E5%BC%BA%E5%BA%A6%E5%92%8C%E7%A1%AC%E5%BA%A6%E7%9A%84%E6%8F%90%E9%AB%98%E6%9C%80%E4%B8%BA%E6%98%8E%E6%98%BE.%E5%9C%A8%E5%BC%B9%E6%80%A7%E6%A8%A1%E9%87%8F%E6%96%B9%E9%9D%A2%2C%E5%8F%AA%E6%9C%89MgO%E7%9A%84%E6%B7%BB%E5%8A%A0%E5%8F%AF%E4%BB%A5%E8%BE%83%E5%A4%A7%E7%A8%8B%E5%BA%A6%E7%9A%84%E6%8F%90%E9%AB%98%E7%94%9F%E7%89%A9%E5%BE%AE%E6%99%B6%E7%8E%BB%E7%92%83%E7%9A%84%E5%BC%B9%E6%80%A7%E6%A8%A1%E9%87%8F%E5%80%BC%2C%E5%85%B6%E5%AE%83%E7%BB%84%E5%88%86%E7%9A%84%E5%BC%95%E5%85%A5%E5%88%99%E5%BD%B1%E5%93%8D%E8%BE%83%E5%B0%8F.7%E7%A7%8D%E6%88%90%E5%88%86%E7%9A%84%E7%94%9F%E7%89%A9%E5%BE%AE%E6%99%B6%E7%8E%BB%E7%92%8320%EF%BD%9E500%E2%84%83%E7%9A%84%E7%BA%BF%E8%86%A8%E8%83%80%E7%B3%BB%E6%95%B0%E5%A4%A7%E8%87%B4%E5%9C%A8%289.1%EF%BD%9E12.5%29%C3%9710-6%2F%E2%84%83%E8%8C%83%E5%9B%B4%E4%B9%8B%E5%86%85%2C%E7%AC%A6%E5%90%88%E9%92%9B%E5%90%88%E9%87%91%E6%B6%82%E5%B1%82%E6%9D%90%E6%96%99%E7%BA%BF%E8%86%A8%E8%83%80%E7%B3%BB%E6%95%B0%E8%BE%83%E4%BD%8E%E7%9A%84%E8%A6%81%E6%B1%82.%E7%BB%BC%E5%90%88%E5%90%84%E7%89%A9%E7%90%86%E6%80%A7%E8%83%BD%E6%8C%87%E6%A0%87%E8%BF%9B%E8%A1%8C%E8%AF%84%E4%BC%B0%2C%E5%BC%95%E5%85%A5CaF2%E7%BB%84%E5%88%86%E7%9A%84%E5%BE%AE%E6%99%B6%E7%8E%BB%E7%92%83%E7%89%A9%E7%90%86%E6%80%A7%E8%83%BD%E6%9C%80%E5%A5%BD.%E6%AF%94%E8%BE%83%E9%80%82%E5%90%88%E7%94%A8%E4%BD%9C%E9%92%9B%E5%90%88%E9%87%91%E8%A1%A8%E9%9D%A2%E6%B6%82%E5%B1%82%E6%9D%90%E6%96%99.%0D%0A%0D%0A%097%E7%A7%8D%E7%94%9F%E7%89%A9%E5%BE%AE%E6%99%B6%E7%8E%BB%E7%92%83%E5%9C%A8%E6%A8%A1%E6%8B%9F%E4%BD%93%E6%B6%B2%E4%B8%AD%E6%B5%B8%E6%B3%A12d%E5%90%8E%E8%A1%A8%E9%9D%A2%E5%9D%87%E6%9C%89%E6%B2%89%E7%A7%AF%E7%9B%B8%E5%87%BA%E7%8E%B0%2C%E7%BB%8F%E8%BF%87EDS%2CXRD%E5%92%8CFTIR%E5%88%86%E6%9E%90%E5%8F%91%E7%8E%B0%E8%A1%A8%E9%9D%A2%E6%B2%89%E7%A7%AF%E7%9B%B8%E4%B8%BB%E8%A6%81%E4%B8%BA%E7%A2%B3%E9%85%B8%E7%A3%B7%E7%81%B0%E7%9F%B3%E4%BB%A5%E5%8F%8A%E5%B0%91%E9%87%8F%E7%9A%84%E7%BE%9F%E5%9F%BA%E7%A3%B7%E7%81%B0%E7%9F%B3.N6%E8%AF%95%E6%A0%B7%E6%B5%B8%E6%B3%A114d%E8%A1%A8%E9%9D%A2%E5%9F%BA%E6%9C%AC%E8%A2%AB%E7%A3%B7%E7%81%B0%E7%9F%B3%E8%A6%86%E7%9B%96%2C21d%E5%90%8E%E5%B7%B2%E7%BB%8F%E7%94%9F%E6%88%90%E4%BA%86%E8%BE%83%E5%8E%9A%E7%9A%84%E4%B8%80%E5%B1%82%E7%A3%B7%E7%81%B0%E7%9F%B3.%E6%BA%B6%E8%83%B6%E5%87%9D%E8%83%B6%E6%B3%95%E5%88%B6%E5%A4%87%E7%9A%84%E6%89%80%E6%9C%89%E8%AF%95%E6%A0%B7%E5%9D%87%E5%85%B7%E6%9C%89%E8%89%AF%E5%A5%BD%E7%9A%84%E7%94%9F%E7%89%A9%E6%B4%BB%E6%80%A7%2C%E4%BD%86%E6%98%AFN3%E8%AF%95%E6%A0%B7%E7%94%9F%E7%89%A9%E6%B4%BB%E6%80%A7%E8%BE%83%E5%85%B6%E4%BB%96%E8%AF%95%E6%A0%B7%E4%BD%8E.%0D%0A%0D%0A%09%E7%BB%BC%E5%90%88%E7%89%A9%E7%90%86%E6%80%A7%E8%83%BD%E5%8F%8A%E7%94%9F%E7%89%A9%E6%B4%BB%E6%80%A7%E7%AD%89%E6%96%B9%E9%9D%A2%E8%80%83%E8%99%91%2C%E5%BC%95%E5%85%A56mol%CAF2%E7%9A%84%E7%94%9F%E7%89%A9%E6%B4%BB%E6%80%A7%E5%BE%AE%E6%99%B6%E7%8E%BB%E7%92%83%E5%85%B7%E6%9C%89%E8%BE%83%E5%A5%BD%E7%9A%84%E7%89%A9%E7%90%86%E6%80%A7%E8%83%BD%E5%8F%8A%E8%89%AF%E5%A5%BD%E7%9A%84%E7%94%9F%E7%89%A9%E6%B4%BB%E6%80%A7%2C%E5%B9%B6%E4%B8%94%E7%BA%BF%E8%86%A8%E8%83%80%E7%B3%BB%E6%95%B0%E4%B8%8E%E9%92%9B%E5%90%88%E9%87%91%E6%8E%A5%E8%BF%91%2C%E9%80%82%E5%90%88%E4%BD%9C%E4%B8%BA%E9%92%9B%E5%90%88%E9%87%91%E8%A1%A8%E9%9D%A2%E6%B6%82%E5%B1%82%E6%9D%90%E6%96%99.
【学位授予单位】：山东大学
【学位级别】：硕士
【学位授予年份】：2012
【分类号】：R318.08
【参考文献】
相关期刊论文 前10条
1 和峰,刘昌胜;骨修复用生物玻璃研究进展[J];玻璃与搪瓷;2004年04期
2 储成林,朱景川,尹钟大,王世栋;医用钛合金及其表面改性[J];材料科学与工艺;1998年02期
3 唐膺，，翁文剑;生物陶瓷的发展与应用[J];材料科学与工程;1994年02期
4 沈卫,顾燕芳,刘昌胜,孙祥明,胡黎明;羟基磷灰石的表面特性[J];硅酸盐通报;1996年01期
5 李文旭;于德珍;王福平;费维栋;;ZrO_2纳米颗粒的添加对ZrO_2/HA复合陶瓷物相和力学性能的影响[J];高校化学工程学报;2007年05期
6 陈晓峰,张晓凯,滕立东,张梅梅;氟磷灰石-氟金云母微晶玻璃的生物活性研究[J];硅酸盐学报;1993年03期
7 程慷果,万菊林,梁开明;氧化锆增韧微晶玻璃的制备[J];硅酸盐学报;1998年03期
8 范德增,莫宣学,翁润生,秦飞;钛及钛合金在医学上的应用研究[J];口腔材料器械杂志;1999年01期
9 黄炳堂,顾卫民,孙荆,鲍贤鸿,戴其昌;钛合金表面生物活性玻璃涂层种植体研究[J];口腔颌面外科杂志;1996年03期
10 曾媛;生物陶瓷材料研究进展[J];上海生物医学工程;2001年03期
相关硕士学位论文 前2条
1 褚颖;磁性可切削生物活性微晶玻璃的研究[D];武汉理工大学;2004年
2 杨巍;用于Ti6Al4V表面生物活性陶瓷涂层材料的设计及制备[D];天津大学;2006年
本文编号：2285379
本文链接：https://www.wllwen.com/yixuelunwen/swyx/2285379.html
