新型铌基高温合金热处理组织性能研究
发布时间:2018-04-24 04:24
本文选题:铌基高温合金 + 组织 ; 参考:《稀有金属材料与工程》2017年08期
【摘要】:研究了热处理对一种HRS定向凝固技术制备Nb/Nb5Si3原位复合材料组织和性能的影响。采用扫描电子显微镜(SEM)、X射线衍射(XRD)和电子探针(EPMA)等分析手段对热处理过程中组织演变进行了分析:铸态合金主要由Nbss、γ-(Nb,Ti)_5Si_3、β-(Nb,Ti)_5Si_3以及初生碳化物组成;热处理后,铸态组织中部分β-(Nb,Ti)_5Si_3向α-(Nb,Ti)_5Si_3转变以及二次碳化物析出,同时硅化物相逐渐溶解或破碎成小块并发生球化;1150℃时效可促进(Nb,Ti)_5Si_3向(Ti,Nb)5Si3转变。热处理后,合金压缩以及室温拉伸强度提高,而1000℃拉伸强度变化不明显;温度对断裂方式有明显影响,低温下为脆性解理断裂,高温下为韧性断裂。
[Abstract]:The effect of heat treatment on the microstructure and properties of Nb/Nb5Si3 in-situ composites prepared by HRS directional solidification technique was studied. The microstructure evolution during heat treatment was analyzed by means of scanning electron microscope (SEM) and electron probe EPMA (EPMA). The as-cast alloy was mainly composed of Nbss, 纬 -NbTiTiSi5Si5Si3, 尾 -NbTiTiSi5SiSn3 and primary carbides. In the as-cast structure, some of the 尾 -NbTi5SiS3 transition to 伪 -nbTiTiTiS3 and secondary carbides precipitation, while the silicide phase gradually dissolves or breaks into small blocks and spheroidized at 1150 鈩,
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